F. Torknik, M. Keyanpour-Rad, A. Maghsoudipour, G. M. Choi,
Volume 13, Issue 1 (3-2016)
Abstract
In order to further enhance the Ni/Ce 0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance for low temperature solid oxide fuel cell (LT-SOFC), a study was conducted on the nanostructuring of NiO/GDC composite by only once wet-infiltration of rhodium chloride precursor. By using electrochemical impedance spectroscopy (EIS) analysis, the effect of only one drop of Rh-infiltrating solution on the anodic polarization resistance was examined using symmetric Ni–GDC20|GDC20|Pt electrolyte-supported cell at 400-600 °C. Nanostructural evolution before and after H 2 reduction at 600 °C and also after anodic performance test was investigated by atomic force microscopy (AFM), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM) techniques in comparison to the anode itself. Despite the fine distribution of Rh-infiltrated nanoparticles having average particle size of 11.7 nm, the results showed ineffectiveness and inability of the Rh nanoparticles to succeed in decreasing of anodic polarization resistance for H 2 oxidation reaction in LT-SOFC.
Jashanpreet Singh, Rana Gill, Satish Kumar, S.k. Mohapatra,
Volume 19, Issue 4 (12-2022)
Abstract
In this paper, an investigation was carried out to test the suitability of potential additive materials in
WOKA 3533 (WC-10Co4Cr) cermet HVOF coating subjected to slurry erosion in ash conditions. The additives
namely molybdenum carbide, yttrium oxide, and zirconium oxide were added in equal percentages (3 wt.%) in
WOKA cermet powder. High-velocity oxy-fuel (HVOF) spraying was performed to develop the additive-based
WOKA cermet coatings. The slurry erosion in ash conditions was tested using the pot tester. Microstructural and
mechanical properties of traditional and additive-based WOKA cermet coatings were also tested in the present
study; for example, microstructure, crystalline phases of as-sprayed coatings, and microhardness. Results present a
comparison of surface erosion wear of different cermet coatings. It was found that the yttrium oxide was a suitable
additive for the WOKA cermet coatings than the molybdenum carbide. However, zirconium oxide is unsuitable for
WOKA cermet coatings in erosion wear applications.
