Iranian Journal of Materials Science and Engineering

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In the present research influences of different combinations of five types of inoculants and four types of nodularizers on eutectic nucleation in ductile cast iron were studied. The alloys were kept at 1320°C for 0, 5, 10, 15 and 20 min under nitrogen atmosphere. Cooling curves and image analysis were used to characterize the influence of holding time and different combinations of inoculants and nodularizers on the graphite morphologies and eutectic nucleation. When dominant morphology of graphite is spheroidal or flake, by decreasing the different combinations of nodularizers and inoculants fading resistance, temperature of eutectic undercooling decreases. Nevertheless, when there is combination of spheroidal, vermicular and flake graphites temperature of eutectic undercooling increases by reduction of material fading resistance.

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Abstract: Strength at elevated temperatures and thermal shock resistance of austempered ductile irons at high temperatures has been less intentioned, because of instability of ausferrite phase. In this research the tensile properties of this iron and pearlitic ductile cast iron have been investigated by short time high temperature tensile tests. Also thermal shock tests were done at the molten lead bath at 1000 􀁱C . In these experiments, at first samples were immersed partially in the molten lead bath for 25 seconds and then either cooled in air or quenched in water. Results of short time high temperature tensile and thermal shock tests showed that ADI samples have higher strength and shock resistance than the pearlitic ductile samples.

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Abstract: Ball mills are used in the last stage of ore processing for grinding raw materials. Forged 70Cr2 alloy steel and Austempered Ductile Iron (ADI) balls are materials from which grinding balls are made for Sarcheshmeh Copper Plant (SCP) ball mills. In the present study wear and impact properties of these two kinds of balls have been investigated. Some balls randomly were selected as samples. They were cut to investigate the cross section under optical and scanning electron microscopes. The microstructure of the sample balls was studied and quantitative measurements of microstructural features were performed. The hardness of different parts of cross sections of balls was measured. The wear resistance of the balls was measured by Pin on Disc method. Repeated dropt test was employed to evaluate impact resistance of the balls. The microstructure of ADI balls consisted of bianitic matrix with graphite nodules and some retained austenite and martensite. Micro cracks and porosities in the cast structure were frequently observed. In the case of forged steel balls the microstructure composed of tempered martensite in outer area and bianitic structure with some tempered martensite in central areas. The wear and impact resistance of forged steel balls were markedly higher than those of ADI balls. The difference was consistent with the differences between the microstructures of the two kinds of balls. Cast structure with microcracks and shrinkage porosities in ADI balls gives rise to lower impact resistance.

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Abstract: The specific rate of breakage is one of the most important factors in evaluation of grinding process especially in ball mill. In this article the effect of ball size and feed size on selection function were investigated using batch grinding circuit on two-iron ore anomaly (B, C) from sangan mine in north of Iran. Eight different monosize fractions were prepared between 2000 and 500 microns, using a 2 sieve series. The specific rates of breakage (Si) were determined from the size distributions at different grinding times, and the specific rates of breakage were compared for three different ball diameters (25.4, 16.6 and 9.6 mm). The results showed that the breakage function of both anomalies is normalizable (independent to the particle size) and it is independent to the ball size. But the specific rate of breakage variate with feed size and ball size. Also optimum size of balls for grinding of this feed obtained to be between 9.6-16.6mm.

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Abstract:

transition and heat affected zones formed during surface remelting (in order to improve wear resistance) with TIG

process has been investigated. Relationship between various TIG parameters and thickness of remelted and heat

affected zones revealed that a high concentrated heat energy is imposed by TIG process which makes it a proper option

for focused surface treatment. Based on microstructural examinations five areas with different microstructure and

microhardness were identified within the surface area. Graphite flakes were totally dissolved within the first area

leading to the transformation of denderitic austenite to plate martensite and the formation of ledeburite within

interdenderites. The main feature of the second area, resulted from the presence of graphite flakes, was the local

melting with a gap in the vicinity of graphite flakes and that of third area was the formation of finer and denser

martensite plates closer to the graphite flakes compared with those formed at a further distance. In the fourth layer

there is a mixture of martensitic and pearlitic matrix while the matrix of fifth layer has no change of microstructure.

In this study the effect of graphite flakes present in a pearlitic grey cast iron on the microstructure of melted,

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Abstract: There have been lots of studies to control the poor hydration resistance of dolomite refractories one of the
most effective solutions has been the addition of magnesia to doloma. Using a co-clinker of magnesia-doloma as a
starting material would provide more homogeneity in the properties of the product and has been published recently.
On the other hand, addition of iron oxide to doloma has been found to increase the hydration resistance. In this paper,
the effect of iron oxide addition on hydration phase analysis and microstructure of two different magnesia- doloma
samples, one with CaO content of 25 wt% and the other one with that of 35 wt% has been investigated. Ten samples
were prepared by pressing followed by firing at 1750 ºC for 3hrs. Results showed that the hydration resistance of the
samples improved by decreasing the CaO content, because CaO is much more prone to hydration comparing to MgO.
Besides, iron oxide addition lead to the formation of iron-containing phases which increased the hydration resistance
of the samples both by capsulating the CaO and MgO grains and by promoting the liquid phase sintering.

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The volatile matter of non-coking coal was used for the reduction of hematite in argon atmosphere at nonisothermal condition. A thermal gravimeter furnace enable to use an 80 mm-height crucible was designed for the experiments to measure the weight changes of about 10 grams samples. A two-layered array of coal and alumina and four-layered array of iron oxide, alumina, coal and alumina was used for the devolatilization and reduction experiments, respectively. The net effect of volatile reduction of Fe 2O3was determined and it was observe that 45% reduction has been achieved. Three distinct regions were recognized on the reduction curve. The reduction of hematite to magnetite could be completely distinguished from the two other regions on the reduction curve. At 600-950°C, the reduction was accelerated. 63% of volatile matter resulted in 25% of total reduction before 600°C while the remaining volatile matter contributed to 75% of the total reduction. From the reduction rate diagram, the stepwise reduction of the iron oxides could be concluded. The partial overlap of the reduction steps were identified through the XRD studies. The starting temperature of magnetite and wüstite reduction were determined at about 585°C and at 810°C, respectively.

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The micro layers micaceous iron oxide and nano-TiO 2 were incorporated into the epoxy resin by mechanical mixing and sonication process. Optical micrographs showed that the number and diameter size of nanoparticle agglomerates were decreased by sonication. The structure and composition of the nanocomposite was determined using transmission electron microscopy which showed the presence of dispersed nano-TiO 2 in the polymer matrix. The anticorrosive properties of the synthesized nano-composites coating were investigated using salt spray, electrochemical impedance spectroscopy and polarization measurement. The EIS results showed that coating resistance increased by addition of micaceous iron oxide micro layers and nano-TiO 2 particles to the epoxy coatings. It was observed that higher corrosion protection of nanocomposite coatings obtained by the addition of 3 %wt micaceous iron oxide and 4%wt nano-TiO 2 into epoxy resin.

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In the present work, iron recovery from a low-grade hematite ore (containing less than 40% iron), which is not applicable in common methods of ironmaking, was studied. Non-coking coal was used as reducing agent. Reduction experiments were performed under various coal to hematite ratios and temperatures. Reduction degree was calculated using the gravimetric method. Reduced samples were subjected to magnetic separation followed by X-ray diffraction analysis. Total iron content, degree of metallization and recovery efficiency in magnetic part were determined by quantitative chemical analysis, which were obtained about 82%, 95% and 64% respectively under optimal conditions. CaO as an additive improved ore reducibility and separation efficiency. The microstructure of reduced samples and final products were analyzed by scanning electron microscopy. Final product with a high degree of metallization can be used in steel making furnaces and charging of blast furnaces which can improve production efficiency and decrease coke usage.

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The field of nanomaterial has greatly advanced in the last decade following a wider range of applications in the fields of electronics, automobiles, construction, and healthcare due to its extraordinary and ever-evolving properties. Synthesis of the nanomaterial plays a crucial role in redefining the current engineering and science field. At the same time, procuring an environment-friendly end product through eco-friendly solutions and sustainable processes is the key to many global problems. Green synthesis of nanomaterials like graphene and its derivatives involves mild reaction conditions and nontoxic precursors because it is simple, cost-effective, relatively reproducible, and often results in more stable materials. This paper primarily focuses on the green synthesis of graphene and its derivatives (graphene oxide & reduced graphene oxide) and geopolymers; a green technology for preparing graphene reinforced geopolymer composites. Various methods used globally for green synthesis of graphene and geopolymer are briefly discussed and this paper tries to integrate these two areas for a green end product. Possible applications of these green composites are also discussed to provide insights on the current growth and developments. 

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1. In this article, the effect of graphite on iron-silicon interactions was investigated. It was found that, as graphite enters the iron structure, it permits further development of iron-silicon reactions. It was found that in the stoichiometric ratio of 1:0.5 of iron and silicon, when graphite is added to the system, simultaneously with the reaction of iron and silicon to form Fe₃Si₅, some amount of carbon can be dissolved in the iron and lead to more diffusion in iron and more iron silicide production. Silicon also reacts with carbon and produces SiC. The more amount of carbon entered into the system, the more growth of SiC occurs, while the production of other iron silicide phases, namely FeSi and Fe₃Si preceded. Finally diffused carbon into the iron reaches a definite amount that can form Fe₃C. In the stoichiometric ratio of 1:1 of iron and silicon, the formation of FeSi and SiC phases is observable. At the same time, the diffusion of carbon occurs in the same as the previous stoichiometric ratio. In the stoichiometric ratio of 1:2 of iron and silicon, compared with the stoichiometric ratio of 1:1, a larger amount of silicon is available and, the FeSi₂ phase can form in addition to FeSi

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Iron oxide nanoparticles has attracted extensively due to their supermagnetic properties, preferred in biomedicine because of their biocompatibility and potential nontoxicity to human beings. Synthesis of iron nanoparticles (FeNPs) was prepared with the help of ferric chloride and ferrous sulphate by using the coprecipitation method. The variation and combination of ferric and ferrous concentrations affect the physical and magnetic properties of iron oxide nanoparticles.  The effect of 0.1 M ferric and ferrous concentration on iron oxide nanoparticles studied separately and in combination. The obtained nanoparticles were characterized by Particle size, zeta potential, Ultraviolet (UV-visible), Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscope (SEM), Thermal gravimetric analysis (TGA), and Vibrating-sample magnetometer (VSM) techniques. Particle size was below 200nm and zeta potential was within the limit for all the batches. UV visible spectra at 224 nm, and FTIR exhibit two peaks at 510 and 594 cm-1, indicating iron oxide NPs and XRD confirmed the crystalline nature of Fe. SEM showed a spherical shape for all batches. The use of a combination of ferric and ferrous is more effective than its individual use. TGA and VSM studies confirmed its magnetic properties.